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Thermodynamics

The Mpemba Effect

In 1969, a Tanzanian schoolboy asked why his hot ice cream mix froze faster than his classmates' cold mix. The answer is still debated by physicists today.

1969

Erasto Mpemba noticed it at age 13. Denis Osborne published the study.

🔥 Hot Sample
80°C
Start Temp80°C
🧊
❄️ Cold Sample
20°C
Start Temp20°C
🧊
Contested Science
Cooling Curves — Temperature vs. Time
🏆 Hot froze first!
Hot sample
Cold sample
Freezing point (0°C)
Proposed Mechanisms

Evaporation reduces hot water mass. Convection currents form differently. Dissolved gases escape. Supercooling is easier. None is universally accepted.

Why It's Disputed

The effect is highly sensitive to container shape, water purity, freezer air flow, and initial conditions. Many labs reproduce it; many can't. Replication is the whole problem.

2016 Study (Burridge)

A Cambridge study found no robust evidence for the Mpemba effect under controlled conditions — reigniting debate. Other teams still claim to observe it consistently.

The Reframe

A schoolboy's question in 1969 still doesn't have a settled answer in 2024. Science doesn't always resolve cleanly — sometimes the most reproducible result is the disagreement itself.